Effect of iron on lipid peroxidation, and enzymatic and non-enzymatic antioxidants and bacoside-A content in medicinal plant Bacopa monnieri L

The effect of Fe was investigated in medicinally important plant, Bacopa monnieri L. and the response on malondialdehyde (MDA) content, superoxide dismutase (SOD), peroxidase (POD) and ascorbate peroxidase (APX) was found different in roots and leaves of the metal treated plants. Iron induced stress was observed as indicated by high level of lipid peroxidation, being more steep increase in leaves than roots. In roots, SOD activity was found to increase in metal treated plants except 80 and 160 microM at 72 h, whereas, it decreased in leaves except 10 and 40 microM after 48 h as compared to their respective controls. Among H2O2 eliminating enzymes, POD activity increased in roots, however, it decreased in leaves except at 10 and 40 microM Fe after 48 h as compared to control. At 24 and 48 h, APX activity and ascorbic acid content followed the similar trend and were found to increase in both parts of the metal treated plants as compared to their respective controls. The level of cysteine content in the roots increased at initial period of exposure; however, no marked change in its content was noticed in leaves. In both roots and leaves, non-protein thiol content was found to increase except at higher metal concentrations at 72 h. The data of proline content have shown significant (p<0.01) increase at 40 microM onwards in both part of the plants after 48 and 72 h. Correlation coefficient was evaluated between metal accumulations with various parameters and also between different antioxidant parameters with MDA. Since the level of bacoside-A (active constituent) content in metal treated plants increases, therefore, it is advisable to assess the biological activity of the plants before using for medicinal purposes, particularly in developing countries.     

Management of Lignite Fly Ash for Improving Soil Fertility and Crop Productivity

Lignite fly ash (LFA), being alkaline and endowed with excellent pozzolanic properties, a silt loam texture, and plant nutrients, has the potential to improve soil quality and productivity. Long-term field trials with groundnut, maize, and sun hemp were carried out to study the effect of LFA on growth and yield. Before crop I was sown, LFA was applied at various doses with and without press mud (an organic waste from the sugar industry, used as an amendment and source of nutrients). LFA with and without press mud was also applied before crops III and V were cultivated. Chemical fertilizer, along with gypsum, humic acid, and biofertilizer, was applied in all treatments, including the control. With one-time and repeat applications of LFA (with and without press mud), yield increased significantly (7.0–89.0%) in relation to the control crop. The press mud enhanced the yield (3.0–15.0%) with different LFA applications. The highest yield LFA dose was 200 t/ha for one-time and repeat applications, the maximum yield being with crop III (combination treatment). One-time and repeat application of LFA (alone and in combination with press mud) improved soil quality and the nutrient content of the produce. The highest dose of LFA (200 t/ha) with and without press mud showed the best residual effects (eco-friendly increases in the yield of succeeding crops). Some increase in trace- and heavy-metal contents and in the level of γ-emitters in soil and crop produce, but well within permissible limits, was observed. Thus, LFA can be used on a large scale to boost soil fertility and productivity with no adverse effects on the soil or crops, which may solve the problem of bulk disposal of fly ash in an eco-friendly manner.     

A review of the PGM industry,deposit models and exploration practices: Implications for Australia's PGM potential

Australia is prospective for platinum group metal (PGM) mineralisation (in particular primary magmatic reef, primary magmatic by-product, late magmatic and hydrothermal, and alluvial placer type) but its known PGM endowment is negligible compared to that of South Africa, Russia, the USA and Canada. Most Australian PGM projects are operated by mid-cap or junior companies and form part of larger, more diverse project portfolios held by these explorers. Most projects were ‘hot’ while market conditions were favourable. However, as other metals became ‘fashionable’ and market conditions for PGM changed, so did the focus of these companies. Pure PGM companies are rare in Australia. The search for and development of PGM-only deposits in Australia are high risk business activities. No new primary PGM deposits have been discovered since the mid to late 1980s and none of the significant deposits that were discovered or evaluated in the 1980s have been mined. This review suggests that at least several A$10 million but more likely several A$100 million were sunk into PGM exploration and development projects but none advanced to the mining stage. The viability of Australian PGM projects is very sensitive to (1) metal prices, (2) the US$/A$ exchange rate, and (3) large capital expenditure requirements relative to the small size of Australian PGM-only deposits. Most PGM-only projects were initiated at times of high PGM prices. However, advanced exploration, feasibility studies and project development always lagged behind the price booms. South Africa, Russia and Canada contain approximately 98% of the known global PGM reserves. This situation has a very negative effect on the Australian PGM industry as the well-endowed nations continue to receive the lion's share of exploration spend and new projects.     

Biphasic reduction model for predicting the impacts of dye-bath constituents on the reduction of tris-azo dye Direct Green-1 by zero valent iron (Fe)

Influence of common dye-bath additives, namely sodium chloride, ammonium sulphate, urea, acetic acid and citric acid, on the reductive decolouration of Direct Green 1 dye in the presence of Fe⁰ was investigated. Organic acids improved dye reduction by augmenting Fe⁰ corrosion, with acetic acid performing better than citric acid. NaCl enhanced the reduction rate by its ‘salting out’ effect on the bulk solution and by Cl⁻ anion-mediated pitting corrosion of iron surface. (NH₄)₂SO₄ induced ‘salting out’ effect accompanied by enhanced iron corrosion by SO₄^2 − anion and buffering effect of NH₄⁺ improved the reduction rates. However, at 2 g/L (NH₄)₂SO₄ concentration, complexating of SO₄^2 − with iron oxides decreased Fe⁰ reactivity. Urea severely compromised the reduction reaction, onus to its chaotropic and ‘salting in’ effect in solution, and due to it masking the Fe⁰ surface. Decolouration obeyed biphasic reduction kinetics (R² > 0.993 in all the cases) exhibiting an initial rapid phase, when more than 95% dye reduction was observed, preceding a tedious phase. Maximum rapid phase reduction rate of 0.955/min was observed at pH 2 in the co-presence of all dye-bath constituents. The developed biphasic model reckoned the influence of each dye-bath additive on decolouration and simulated well with the experimental data obtained at pH 2.     

Assessment of temporal variation in water quality of some important rivers in middle Gangetic plains, India

The study explains water quality of three important tributaries of the Ganga River in the middle Gangetic plains in India. Seasonal changes in the water quality of the studied rivers: Gandak, Ghaghra, and Sone were observed. During monsoon, several water quality parameters show considerable changes due to increased runoff from the catchments and other seasonal factors. Multivariate discriminant analysis delineated a few parameters responsible for temporal variation in water quality. Seasonal variation in water quality of the Gandak River was rendered by seven parameters??turbidity, sulfate, pH, phosphate, water temperature, total alkalinity, and sodium, while total alkalinity and water temperature were responsible for seasonal discrimination in water quality of Ghaghra River. Water temperature, turbidity, total dissolved solids, total suspended solids, calcium, and phosphate were important for seasonal discrimination in water quality of Sone River. The seasonal changes in water quality of the rivers were due to seasonal effects and catchment characteristics. The discriminant functions classified most of the cases correctly.     

Distribution of Metals in the Edible Plants Grown at Jajmau, Kanpur (India) Receiving Treated Tannery Wastewater: Relation with Physico-Chemical Properties of the Soil

The implications of metal contamination of agricultural soils due to long term irrigation with treated industrial wastewater and their subsequent accumulation in the vegetables/crops growing on such soils has been assessed in an area of industrial complex, Jajmau, Kanpur (India). Physico-chemical properties of the soil were also studied. The soil and vegetables/crops were sampled from an area of 2100 acre agricultural land and analyzed for physico-chemical properties and metal accumulation in different parts of the plants. The comparison of the data of physico-chemical properties of control and contaminated soil showed that salinity, electrical conductivity, available phosphorous, sodium and potassium content (both water soluble and exchangeable) were found high in contaminated soil. The analysis of plant available metal content in the soil showed the highest level of Fe, which ranged from 529.02 to 2615 μg g⁻¹ dw and lowest level of Ni (3.12 to 10.51 μg g⁻¹ dw). The analysis of the results revealed that accumulation of toxic metal Cr in leafy vegetables was found more than fruit bearing vegetables/crops. Thus, it is recommended that the leafy vegetables are unsuitable to grow in such contaminated sites. It is important to note that toxic metal, Ni was not detected in all the plants. The edible part of the vegetables (under ground) such as, garlic (19.27 μg g⁻¹ dw), potato (11.81 μg g⁻¹ dw) and turmeric (20.86 μg g⁻¹ dw) has accumulated lowest level of toxic metal, Cr than leafy and fruit bearing vegetables. In some fruit part of vegetables such as, bitter gourd, egg plant, jack tree, maize and okra, the accumulation of Cr was not detected and may be grown in this area.     

Influence of ATD versus PMHS reference sensor inputs on computational brain response in frontal impacts to advanced combat helmet (ACH)

ABSTRACT

Objective: This study analyzed the influence of reference sensor inputs from anthropomorphic test devices (ATDs) versus postmortem human subjects (PMHSs) on simulations of frontal blunt impacts to the advanced combat helmet (ACH).

Methods: A rigid-arm pendulum was used to generate frontal impacts to ACHs mounted on ATDs and PMHS. An appropriately sized ACH was selected according to standard fitting guidelines. The National Operating Committee on Standards for Athletic Equipment (NOCSAE) head was selected for ATD tests due to shape features that enabled a realistic helmet fit. A custom procedure was used to mount a reference sensor internally near the center of gravity (CG) of the PMHS. Reference sensor data from the head CG were used as inputs for the Simulated Injury Monitor (SIMon). Brain responses were assessed with the cumulative strain damage measure set at 10%, or CSDM(10).

Results: Compared to ATD tests, PMHS tests produced 18.7% higher peak linear accelerations and 5.2% higher peak angular velocities. Average times to peak for linear accelerations were relatively similar between ATDs (5.5?ms) and PMHSs (5.8?ms). However, times to peak for angular velocities were higher by a factor of up to 3.4 for PMHSs compared to ATDs. Values for were also higher by a factor of up to 13.1 when PMHS inputs were used for SIMon.

Conclusions: The preliminary findings of this work indicate that small differences in ATD versus PMHS head kinematics could lead to large differences in strain-derived brain injury metrics such as CSDM.     

Adsorptive removal and recovery of the azo dye Eriochrome Black T

Bottom ash and de-oiled soya have been evaluated as potential adsorbents for the removal of a water soluble azo dye. The characterization of the adsorbents has been performed using infrared spectroscopy and differential thermal analysis. A batch of adsorption method has been adopted for studying the effects of pH, adsorbate concentration, and particle size on the adsorption process. The experimental data were tested using Langmuir, Freundlich, Tempkin, and Dubinin–Radushkevich isotherms and their parameter constants were determined. The thermodynamics showed that the process is spontaneous and exothermic. The kinetic studies revealed that the adsorption process follows first-order kinetics. A fixed-bed adsorption experiment resulted in 89% and 94% saturation of bottom ash and de-oiled soya, respectively, indicating that both adsorbents can be potentially economical.     

Economic costs of protecting islands from invasive alien species

Biological invasions represent a key threat to insular systems and have pronounced impacts across environments and economies. The ecological impacts have received substantial focus, but the socioeconomic impacts are poorly synthesized across spatial and temporal scales. We used the InvaCost database, the most comprehensive assessment of published economic costs of invasive species, to assess economic impacts on islands worldwide. We analyzed socioeconomic costs across differing expenditure types and examined temporal trends across islands that differ in their political geography—island nation states, overseas territories, and islands of continental countries. Over US$36 billion in total costs (including damages and management) has occurred on islands from 1965 to 2020 due to invasive species’ impacts. Nation states incurred the greatest total and management costs, and islands of continental countries incurred costs of similar magnitude, both far higher than those in overseas territories. Damage-loss costs were significantly lower, but with qualitatively similar patterns across differing political geographies. The predominance of management spending differs from the pattern found for most countries examined and suggests important knowledge gaps in the extent of many damage-related socioeconomic impacts. Nation states spent the greatest proportion of their gross domestic products countering these costs, at least 1 order of magnitude higher than other locations. Most costs were borne by authorities and stakeholders, demonstrating the key role of governmental and nongovernmental bodies in addressing island invasions. Temporal trends revealed cost increases across all island types, potentially reflecting efforts to tackle invasive species at larger, more socially complex scales. Nevertheless, the already high total economic costs of island invasions substantiate the role of biosecurity in reducing and preventing invasive species arrivals to reduce strains on limited financial resources and avoid threats to sustainable development goals.